文献类型：期刊文献

英文题名：Synthesis of tertiary propargylamines via a rationally designed multicomponent reaction of primary amines, formaldehyde, arylboronic acids and alkynes

作者：Wang, Jiayi[1,2];Shen, Qiaoying[1];Li, Pinzhen[1];Peng, Yanqing[1];Song, Gonghua[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China;[2]Shanghai Res Inst Chem Ind, Shanghai Key Lab Catalysis Technol Polyolefins, Shanghai 200062, Peoples R China

年份：2014

卷号：12

期号：30

起止页码：5597

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;EI(收录号：20142917945143);WOS:【SCI-EXPANDED(收录号:WOS:000339138300009)，CCR-EXPANDED(收录号:WOS:000339138300009)】；

基金：Financial support for this work from the National Basic Research Program of China (973 program) (grant no. 2010CB126101), the National Natural Science Foundation of China (grant 20972052) and the Shanghai Key Laboratory of Catalysis Technology for Polyolefins (LCTP-201301) are gratefully acknowledged.

语种：英文

外文关键词：Amines - Hydrocarbons

摘要：A novel approach for the synthesis of tertiary propargylamines is achieved through a Cu(OAc)(2)-catalyzed multicomponent reaction of primary amines, formaldehyde, arylboronic acids and allynes, where a combination of PBM and A(3)-coupling reactions is involved in this new multicomponent reaction.