文献类型：期刊文献

英文题名：Heterocyclic polymerization modified g-C 3 N 4 nanotube with advanced charge separation for solar light driven degradation of ciprofloxacin

作者：Dai, Jinxiang[1];Liu, Zhixin[1];Song, Yanyu[1];Liu, Yongdi[1];Nghiem, Long D.[2];Wang, Qilin[2];Liu, Wen[3];Sun, Xianbo[1];Cai, Zhengqing[1,4]

机构：[1]East China Univ Sci & Technol, Natl Engn Res Ctr Ind Wastewater Detoxicat & Resou, Shanghai 200237, Peoples R China;[2]Univ Technol Sydney, Ctr Technol Water & Wastewater, Sch Civil & Environm Engn, Ultimo, NSW 2007, Australia;[3]Peking Univ, Coll Environm Sci & Engn, Key Lab Water & Sediment Sci, Minist Educ, Beijing 100871, Peoples R China;[4]Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200237, Peoples R China

年份：2024

卷号：348

外文期刊名：SEPARATION AND PURIFICATION TECHNOLOGY

收录：;EI(收录号：20241816011689);WOS:【SCI-EXPANDED(收录号:WOS:001236643000001)】；

基金：This work was supported by Natural Science Foundation of Shanghai (21ZR1415600) , National Natural Science Foundation of China (41807340, 22176061) , and Science & Technology Commission of Shanghai Municipality (STCSM, 21230712000) .

语种：英文

外文关键词：Photocatalytic; Ciprofloxacin; 6-triaminopyrimidine; Heterocycle polymerization

摘要：A novel heterocyclic polymerized g-C 3 N 4 nanotube was prepared by thermal polycondensation using urea and 2,4,6-triaminopyrimidine (TAP). The TAP-polymerized g-C 3 N 4 composite with 0.5 wt% TAP content showed the highest photocatalytic activity for ciprofloxacin (CIP) degradation under solar irradiation. The optimal composite derived from urea achieved - 10.8 and - 7.5 time of CIP degradation activity when compared with TAPpolymerized g-C 3 N 4 derived from melamine and thiourea. The copolymerization of TAP molecules reduces the pi electron defects in the g-C 3 N 4 conjugated system thus accelerates the migration of photogenerated carriers. The doping of TAP in g-C 3 N 4 reduces its band gap, which enhances the light absorption capacity and improves the utilization efficiency of visible light. The fluffy porous nanotube structure of the material endows it with unique surface morphology and excellent photoelectric characteristic. Electron spin resonance (ESR) and probe technology were used for qualitative or quantitative detection of free radicals in this work. Superoxide radicals ( O & sdot; - 2 ) played the major roles in the photodegradation of CIP. Recycling experiments displayed the high stability and activity of the modified materials, which is potentially applicable in practical engineering. Moreover, the photodegradation pathways and mechanisms of CIP were proposed and its toxicity evolution was assessed in this study. This work revealed the specific application of heterocyclic polymerization in modifying g-C 3 N 4 material and provided unique insights for its application in photocatalytic degradation of antibiotic.