文献类型：期刊文献

中文题名：烟草基活性炭材料用于电化学超级电容器（英文）

英文题名：An activated carbon derived from tobacco waste for use as a supercapacitor electrode material

作者：陈辉[1];郭燕川[2];王富[3];王刚[1];祁佩荣[1];郭旭虹[1,4];代斌[1];于锋[1]

机构：[1]石河子大学化学化工学院,新疆兵团绿色化工过程重点实验室,新疆石河子832003;[2]中国科学院理化技术研究所,北京100190;[3]中国科学院新疆理化技术研究所,新疆乌鲁木齐830011;[4]华东理工大学化工学院化学工程联合国家重点实验室,上海200237

年份：2017

卷号：32

期号：6

起止页码：592

中文期刊名：新型炭材料

外文期刊名：New Carbon Materials

收录：CSTPCD;;EI(收录号：20182105222934);Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000423505900013)】；北大核心:【北大核心2014】；CSCD:【CSCD2017_2018】；

基金：Doctor Foundation of Bingtuan (2014BB004); Program of Science and Technology Innovation Team in Bingtuan (2015BD003); Program for Changjiang Scholars, Innovative Research Team in University (IRT_15R46).

语种：中文

中文关键词：超级电容器;活性炭;烟草;能量转化与储存

外文关键词：Supercapacitor; Activated carbon; Tobacco; Energy conversion and storage

摘要：烟草基活性炭(TAC)成功制备并用于超级电容器电极材料。由烟草出发,通过一步水热法,进而热解得到烟草基多孔碳(TPC),比表面积为111.25 m^2·g^(-1),孔容为0.11 cm^3·g^(-1),平均孔直径1.77 nm,在0.5 A·g^(-1)电流下,比电容为37 F·g^(-1)。通过碱活化得到TAC,具有较高的比表面积1297.6 m^2·g^(-1),大的孔容0.52 cm^3·g^(-1),和平均孔直径0.52 nm。在0.5 A·g^(-1)电流下,比电容可达148 F·g^(-1)。两电极体系下具有120 F·g^(-1)的比电容值,在1 A·g^(-1)下经过9 000次循环后,容量没有损失。
A tobacco-derived activated carbon(TAC)was prepared from tobacco waste using KOH activation with a KOH/tobacco carbon mass ratio of3at800℃for1h,and was used as an electrode material for a supercapacitor.The tobacco waste was hydrothermally treated in a10%(v/v)HCl solution to remove metallic impurities and carbonized before activation.The carbonized tobacco has a low Brunauer Emmett Teller(BET)surface area of111.25m2·g1,a pore volume of0.11cm3·g-1,an average pore diameter of1.77nm and a specific capacitance of37F·g-1at a current density of0.5A·g-1.The TAC has a high BET surface area of1297.6m2·g-1,a large pore volume of0.52cm3·g-1,and a pore size distribution with a median pore size of0.52nm.It has a specific capacitance of148F·g1at a current density of0.5A·g1in a6M KOH electrolyte,and an excellent cycling stability with no capacitance fade after9000cycles at a current density of1A·g-1.