文献类型：期刊文献

英文题名：Hollow-Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications

作者：Li, Yongsheng[1];Shi, Jianlin[1,2]

机构：[1]E China Univ Sci & Technol, Lab Low Dimens Mat Chem, Sch Mat Sci & Engn, Key Lab Ultrafine Mat,Minist Educ, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 200050, Peoples R China

年份：2014

卷号：26

期号：20

起止页码：3176

外文期刊名：ADVANCED MATERIALS

收录：;EI(收录号：20142217776660);WOS:【SCI-EXPANDED(收录号:WOS:000336999800001)】；

基金：The authors gratefully acknowledge financial support by the 973 Program (Grant Nos. 2012CB933602 and 2013CB933200), the NSFC (Grant Nos. 51172070, 51132009, 51202068); the Program for New Century Excellent Talents in University (NCET-10-0379); the Shu Guang project (Grant No. 11SG30); and the Fundamental Research Funds for the Central Universities (Grant Nos. WD1114002 and WD1124010).

语种：英文

外文关键词：Diseases - Nanoparticles - Biocompatibility - Network architecture - Catalysis - Storage (materials) - Synthesis (chemical) - Targeted drug delivery - Adsorption - Controlled drug delivery

摘要：Hollow-structured mesoporous materials (HMMs), as a kind of mesoporous material with unique morphology, have been of great interest in the past decade because of the subtle combination of the hollow architecture with the mesoporous nanostructure. Benefitting from the merits of low density, large void space, large specific surface area, and, especially, the good biocompatibility, HMMs present promising application prospects in various fields, such as adsorption and storage, confined catalysis when catalytically active species are incorporated in the core and/or shell, controlled drug release, targeted drug delivery, and simultaneous diagnosis and therapy of cancers when the surface and/or core of the HMMs are functionalized with functional ligands and/or nanoparticles, and so on. In this review, recent progress in the design, synthesis, functionalization, and applications of hollow mesoporous materials are discussed. Two main synthetic strategies, soft-templating and hard-templating routes, are broadly sorted and described in detail. Progress in the main application aspects of HMMs, such as adsorption and storage, catalysis, and biomedicine, are also discussed in detail in this article, in terms of the unique features of the combined large void space in the core and the mesoporous network in the shell. Functionalization of the core and pore/outer surfaces with functional organic groups and/or nanoparticles, and their performance, are summarized in this article. Finally, an outlook of their prospects and challenges in terms of their controlled synthesis and scaled application is presented.