文献类型：期刊文献

英文题名：Dye-sensitized solar cells for efficient power generation under ambient lighting

作者：Freitag, Marina[1,6];Teuscher, Joel[2];Saygili, Yasemin[1];Zhang, Xiaoyu[3,4];Giordano, Fabrizio[5];Liska, Paul[5];Hua, Jianli[3,4];Zakeeruddin, Shaik M.[5];Moser, Jacques-E.[2];Gratzel, Michael[5];Hagfeldt, Anders[1]

机构：[1]Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photomol Sci, CH-1015 Lausanne, Switzerland;[2]Ecole Polytech Fed Lausanne, Photochem Dynam Grp, CH-1015 Lausanne, Switzerland;[3]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[4]East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[5]Ecole Polytech Fed Lausanne, Inst Chem Sci, Lab Photon & Interfaces, Engn, CH-1015 Lausanne, Switzerland;[6]Uppsala Univ, Angstrom Lab, Dept Chem, S-75126 Uppsala, Sweden

年份：2017

卷号：11

期号：6

起止页码：372

外文期刊名：NATURE PHOTONICS

收录：;EI(收录号：20171803628214);WOS:【SCI-EXPANDED(收录号:WOS:000402602500013)】；

基金：We acknowledge the Swiss National Science Foundation for financial support with the project entitled 'Fundamental studies of mesoscopic devices for solar energy conversion', project no. 200021_157135/1, and the NCCR MUST research instrument. J.H. and X.Y. thank NSFC/China (21421004 and 91233207) and the Programme of Introducing Talents of Discipline to Universities (B16017). We appreciate the technical support of R. Humphry-Baker, P. Comte and J.-D. Decoppet. We are also very grateful to G24power for the comparative measurements of the GaAs Alta solar cells under indoor-light conditions.

语种：英文

外文关键词：Efficiency - Lighting - Copper compounds - Heterojunctions - Wireless sensor networks

摘要：Solar cells that operate efficiently under indoor lighting are of great practical interest as they can serve as electric power sources for portable electronics and devices for wireless sensor networks or the Internet of Things. Here, we demonstrate a dye-sensitized solar cell (DSC) that achieves very high power-conversion efficiencies (PCEs) under ambient light conditions. Our photosystem combines two judiciously designed sensitizers, coded D35 and XY1, with the copper complex Cu(II/I)(tmby) as a redox shuttle (tmby, 4,4', 6,6'-tetramethyl-2,2'-bipyridine), and features a high open-circuit photovoltage of 1.1 V. The DSC achieves an external quantum efficiency for photocurrent generation that exceeds 90% across the whole visible domain from 400 to 650 nm, and achieves power outputs of 15.6 and 88.5 mu W cm(-2) at 200 and 1,000 lux, respectively, under illumination from a model Osram 930 warm-white fluorescent light tube. This translates into a PCE of 28.9%.