文献类型：期刊文献

中文题名：氨基改性聚醚型聚硅氧烷的制备及其柔软性能研究

英文题名：Preparation of Amino Modified Polyether Polysiloxanes and their Softness on Fabrics

作者：安秋凤[1];李临生[2];陈孔常[1]

机构：[1]华东理工大学化学与制药学院,上海210037;[2]西北轻工业学院,咸阳712081

年份：2001

卷号：14

期号：4

起止页码：399

中文期刊名：功能高分子学报

外文期刊名：Journal of Functional Polymers

收录：CSTPCD;;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：氨基改性聚醚型聚硅氧烷;织物柔软剂;制备;整理剂;柔软性能

外文关键词：amino modified polyether polysiloxane; polyether /epoxy functional silicone; fabric softener

摘要：用含氢硅油、烯丙基缩水甘油醚、烯基聚醚的硅氢化加成产物—聚醚 /环氧硅油与胺反应制得了氨基改性聚醚型聚硅氧烷 (APEPS) ,对其结构与性能进行了表征和研究。结果表明 ,含氢硅油分子量、有机胺结构、氨基改性聚醚型聚硅氧烷的硅含量对APEPS性能有影响。提高硅含量、增加氨值 ,可改善APEPS的柔软性与滑爽感 ,但对织物的吸湿性影响不大。
Amino modified polyether polysiloxanes (APEPS) were prepared by the reaction of amines with polyether /epoxy functional silicone, which is formed from hydrosilylation of methyl hydrogen silicone with allyl gylcidyl ether and polyoxyalkylene containing vinyl group. The structure and properties of APEPS was studied and characterized. The results showed that the average molecular weight of methyl hydrogen silicone, amine structure and Si content in amino modified polyether polysiloxanes have some effects on APEPS performance. By increasing Si content and amino equivalent of APEPS, the softness and smoothness of finished fabrics is improved, but fabric rewettability is little changed.