文献类型：期刊文献

中文题名：金属壁与催化层一体化汽车尾气净化催化剂

英文题名：Treatment of Automobile Tail Gas by Integral Whole Catalyst from Metal Wall and Catalytic Layer

作者：应卫勇[1];龟山秀雄[2]

机构：[1]华东理工大学化学工程系,上海200237;[2]东京农工大学工学部,日本东京1840012

年份：2000

卷号：41

期号：4

起止页码：185

中文期刊名：化学世界

外文期刊名：Chemical World

收录：CSCD:【CSCD2011_2012】；

基金：国家教委留学回国人员基金!项目 ( 972 40 )

语种：中文

中文关键词：汽车尾气净化催化剂;孔径分布;催化性能

外文关键词：treatment of automobile tail gas; catalyst; pore size distribution; reduction of NO; oxidation of C 3H 6 and CO

摘要：开发了用于汽车尾气净化的金属壁与催化层一体化催化剂。该催化剂由金属表面氧化层载体和催化组分所组成。比较了孔径分布、比表面积、催化组分负载量对催化性能的影响 ,并讨论了空速对催化性能的影响。
The catalyst, from a metal wall and catalytic layer prepared by anodic oxidation, hydration and impregnation of the catalytic composition, was investigated for the treatment of automobile tail gas. The properties of the catalyst were measured in the plug flow integrated reactor at the conditions of space velocity from 10000 h -1 to 30000 h -1 , inlet concentrations of propylene 9.94×10 -4 , NO 1.015×10 -3 ,CO 5.06×10 -4 and oxygen 4.24×10 -3 . The performance of the catalyst with large specific area and high loading is better than that with small specific area and low loading. Over the catalyst treated at 80℃ for 1 hour in the impregnation solution, at the space velocity of 10000 h -1 , the temperatures for the 100% conversion of C 3H 6, NO and CO were 380℃,400℃ and 300℃, respectively.