文献类型：期刊文献

中文题名：Controlled Radical Polymerization of Styrene in the Presence of Different Copper Complexes and Organic Halides

英文题名：Controlled Radical Polymerization of Styrene in the Presence of Different Copper Complexes and Organic Halides

作者：CHENG Guang lou, HU Chun pu \{**\} and YING Sheng kang (Laboratory of Living Polymerization, East China University of Science and Technology, Shanghai 200237, P.R. China) (Received August 28, 1998)

机构：[1]Laboratory of Living Polymerization,East China University of Science and Technology,Shanghai 200237,P.R.China

年份：1999

卷号：15

期号：4

起止页码：358

中文期刊名：Chemical Research in Chinese Universities

外文期刊名：高等学校化学研究（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2011_2012】；

语种：英文

中文关键词：ATRP;Living/controlled;radical;polymerization;1;10;Phenanthroline;4;7;Diphenyl;1;10;phenanthroline;Cuprous;halides;Styrene

外文关键词：ATRP, Living/controlled radical polymerization, 1,10 Phenanthroline, 4,7 Diphenyl 1,10 phenanthroline, Cuprous halides, Styrene

摘要：The polymerization behaviors of Styrene (St) in the presence of CuX/L [X=Cl or Br; L= 2,2 bipyridine (bpy), 1,10 phenanthroline (phen) or 4,7 diphenyl 1,10 phenanthroline (DPP) ] and R X (R=trichloromethyl, benzyl or allyl; X=Cl or Br) have been studied and examined. In a CuCl/bpy/RCl/St system, a bimodal GPC peak at the early stage of polymerization was observed, and a concept of multi active species was proposed to explain this phenomenon. In a CuCl/phen (DPP)/RCl/St system, the \%M\%\-n of polystyrene (PS) increased linearly with St conversion and ln[M] o/[M] also increased linearly with time, indicating the living nature of this system. Furthermore, the stability of the propagating active species in a CuBr/phen/RBr/St system is higher than that in the CuBr/phen/RBr/St system.
The polymerization behaviors of Styrene (St) in the presence of CuX/L [X=Cl or Br; L= 2,2 bipyridine (bpy), 1,10 phenanthroline (phen) or 4,7 diphenyl 1,10 phenanthroline (DPP) ] and R X (R=trichloromethyl, benzyl or allyl; X=Cl or Br) have been studied and examined. In a CuCl/bpy/RCl/St system, a bimodal GPC peak at the early stage of polymerization was observed, and a concept of multi active species was proposed to explain this phenomenon. In a CuCl/phen (DPP)/RCl/St system, the \%M\%\-n of polystyrene (PS) increased linearly with St conversion and ln[M] o/[M] also increased linearly with time, indicating the living nature of this system. Furthermore, the stability of the propagating active species in a CuBr/phen/RBr/St system is higher than that in the CuBr/phen/RBr/St system.