文献类型：期刊文献

中文题名：“饥饿”反应器中苯乙烯聚合动力学

英文题名：Kinetics of STY Free Radical Polymerization in Continuous Phase Semi-Batch Polymerization Reactor

作者：曹贵平[1];乐慧慧[1];张明华[1];沈景慧[1];朱中南[1]

机构：[1]联合化学反应工程研究所华东理工大学分所,国家重点化学工程联合实验室

年份：1995

卷号：9

期号：1

起止页码：52

中文期刊名：高校化学工程学报

外文期刊名：Journal of Chemical Engineering of Chinese Universities

收录：CSTPCD;;Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：饥饿反应器;苯乙烯;聚合动力学;模型参数

外文关键词：Polymerization reactor,Styrene, Kinetics

摘要：本文对“饥饿”反应器中ＡＩＢＮ引发苯乙烯聚合行为进行了详细的研究，建立了相应的聚合动力学模型。在模型中，考虑了由于初级自由基与单体反应生成单体自由基时所消耗的单体量，并将链终止速率常数与聚合物的累积数均链长进行校正。
Kinetics of STY free radical polymerization in a continuous phase semi-batch polymerization reactor was studied. In the reactor. monomer and initiator were fed at a constant small rate into a fixed amount of solvent. This type of reactor is useful in the production of low molecular weight polymer which can be used to make coating and adhesive formulations. The kinetics model incorporated the rate of monomer consumption due to the reaction of primary radicals with monomer and the chain length dependence of the termination rate constant on the cumulative degree of polymerization.The model constants were regressed with the help of experimental data.