文献类型：期刊文献

英文题名：Biphasic Fe7S8@MnS heterostructure embedded in sulfur-doped carbon matrix as anode for Li-ion batteries

作者：Zhou, Jiajing[1];Tan, Xiaoping[2,3];Chen, Hongyan[1];Wang, Yaqian[1];Li, Zhimiao[1];Zhang, Wei[1];Guo, Fuyuan[1];Chen, Yue[1];Xu, Yunlong[1];Zhang, Huang[2,3]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China;[2]Northwestern Polytech Univ, Inst Flexible Elect IFE, Xian 710072, Peoples R China;[3]Northwestern Polytech Univ, Ningbo Inst, Ningbo 315103, Peoples R China

年份：2021

卷号：886

外文期刊名：JOURNAL OF ALLOYS AND COMPOUNDS

收录：;EI(收录号：20213010670338);WOS:【SCI-EXPANDED(收录号:WOS:000697777600002)】；

基金：This work is partially supported by the Shanghai Nanotechnology Special Foundation (No. 11nm0500900) , Shanghai Leading Academic Discipline Project (B502) , Shanghai Key Laboratory Project (08DZ2230500) , Ningbo Natural Science Foundation (202003N4055) , Natural Science Basic Research Program of Shaanxi (2021JQ-110) and the Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Transition metal chalcogenides; Heterostructure; Metal-organic frameworks; Li-ion batteries; Anode materials

摘要：Transition metal chalcogenides have been regarded as promising anode candidates for lithium-ion batteries, featured by their high capacity and abundant material choice. However, their practical implementation was hindered by the poor reaction kinetics and rapid capacity fading due to their low electronic conductivity and severe volume variation upon the (de-)lithiation processes. Here, we have successfully fabricated the biphasic Fe7S8@MnS heterostructure embedded in sulfur-doped carbon matrix by direct sulfidation of Fe/ Mn bimetal-organic frameworks. The biphasic heterostructure and the porous carbon frameworks can create abundant phase boundaries and multiple conductive channels for change transfer, thus improving the electronic conductivity and contact area with electrolyte, leading to facilitated charge transfer cap-ability. As a result, the Fe7S8@MnS/C composites exhibit superior lithium storage performance with a specific capacity of 917 mA h g-1 at 0.1 A g-1 and maintain at 581 mA h g-1 after 500 cycles at 1 A g-1. This work provides an efficient strategy for constructing multiphase nanomaterials towards high performance anodes for Li-ion batteries. (c) 2021 Elsevier B.V. All rights reserved.