文献类型：期刊文献

英文题名：Organocatalytic Reactions of α-Trifluoromethylated Esters with Terminal Alkenes at Room Temperature

作者：Wang, Qi[1,2,3];Huan, Feng[1];Shen, Haiming[1];Xiao, Ji-Chang[1];Gao, Min[1];Yang, Xianjin[1];Murahashi, Shun-Ichi;Chen, Qing-Yun[1];Guo, Yong[1]

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2013

卷号：78

期号：24

起止页码：12525

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20140117150217);WOS:【SCI-EXPANDED(收录号:WOS:000329077900023)，CCR-EXPANDED(收录号:WOS:000329077900023)】；

基金：This work was supported by National Basic Research Program of China (973 Program) (No. 2012CB821600), National Natural Science Foundation of China (No. 21032006, 21172241) and Shanghai Science and Technology Commission (11ZR1445700).

语种：英文

外文关键词：Phosphorus compounds - Hydrocarbons - Addition reactions

摘要：CF3-containing esters smoothly reacted with electron-deficient alkenes in the presence of a phosphine (2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl) organocatalyst at room temperature in an aerobic atmosphere. These Michael reactions efficiently provided products with a CF3 quaternary carbon center.