文献类型：期刊文献

英文题名：Complex reaction kinetics network of hexane hydroisomerization

作者：Zhu, ZL; Li, CL; Huang, GX

年份：1996

卷号：54

期号：10

起止页码：972

外文期刊名：ACTA CHIMICA SINICA

收录：;WOS:【SCI-EXPANDED(收录号:WOS:A1996VU23600007)】；

语种：英文

摘要：The kinetics of hydroisomerization of five hexane isomers over Pd/H-Mordenite catalyst has been studied at a temperature range 210 similar to 260 degrees C, total pressure of 1.96 MPa and H-2/hexane mole ratio of 8 in a combination unit of catalytic pressure microreactor and gas chromatograph. The results show that this complex reaction system could be assumed to be preudomonomolecular in the case of constant total pressure and constant H-2/hexane ratio. All the kinetic parameters of this reaction network have been calculated and the reaction activity energies are between 88.2 similar to 228kJ/mol.