文献类型：期刊文献

中文题名：一种活性极高的端烯加氢催化体系

英文题名：EXTREMELY ACTIVE CATALYST SYSTEM FOR THE HYDROGENATION OF TERMINAL OLEFINS

作者：范荫恒[1];廖世健[2];徐筠[2];钱延龙[3];黄吉玲[3]

机构：[1]辽宁师范大学化学系;[2]中国科学院大连化学物理研究所;[3]华东理工大学应用化学研究所

年份：1998

卷号：19

期号：5

起止页码：389

中文期刊名：催化学报

收录：CSTPCD;;Scopus;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

基金：中国科学院上海有机化学研究所金属有机化学开放实验室;辽宁省教委科研基金

语种：中文

中文关键词：茂钛配合物;纳米级;氢化钠;加氢;端烯;催化剂

外文关键词：Titanocene, Nanometric sodium hydride, Catalytic hydrogenation, Terminal olefin, Catalyst efficiency

摘要：钛配合物还原剂双组分催化剂对不饱和烃类的加氢反应引起了人们的广泛关注．我们曾报道过以纳米氢化钠（ＮａＨ）为助剂（还原剂）与茂钛配合物组成的双组分催化剂对不饱和烃类的加氢反应［１，２］，这类催化剂在温和条件下显示出很高的活性，但稳定性稍差．最近我们...
The hydrogenation of terminal olefins was catalyzed by titanocenes with various substituted groups in combination with nanometric sodium hydride. When the steric hindrance of the substituted group on the cyclopentadienyl ring was large (for instance, six membered ring or seven membered ring), the titanium complex gave extremely high catalytic activity with fairly good stability. At normal temperature and pressure, a maximum turnover frequency (TOF initial ) of 298 mol/(mol·s) in the hydrogenation of 1 hexene and a turnover (TO) of 118000 mol/mol in the hydrogenation of styrene were obtained. These catalysts exhibited very special selectivity to the olefin substrate. Only the terminal olefins could be hydrogenated by using this kind of catalytic system.