文献类型：期刊文献

英文题名：Methane activation over a boron nitride catalyst driven by in situ formed molecular water

作者：Wang, Yang[1];Zhao, Liyang[2,3];Shi, Lei[1];Sheng, Jian[1];Zhang, Weiping[1];Cao, Xiao-Ming[2,3];Hu, Peijun[2,3];Lu, An-Hui[1]

机构：[1]Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China;[2]East China Univ Sci & Technol, Ctr Computat Chem, Shanghai 200237, Peoples R China;[3]East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

年份：2018

卷号：8

期号：8

起止页码：2051

外文期刊名：CATALYSIS SCIENCE & TECHNOLOGY

收录：;EI(收录号：20181805120881);WOS:【SCI-EXPANDED(收录号:WOS:000433517700004)】；

基金：This study was supported by the State Key Program of the National Natural Science Foundation of China (21733002 and 21333003) and the National Natural Science Foundation of China (U1462120 and 21673072).

语种：英文

外文关键词：Nitrides - III-V semiconductors - Methane - Chemical activation

摘要：Boron nitride can catalyze the oxidative conversion of methane to valuable chemicals with minor formation of CO2. B-O-H groups, both originally existing and in situ generated in the reaction, promote the activation of O-2 and CH4, and a novel H2O-assisted O-2 and CH4 synergetic mutual activation mechanism was proposed.