文献类型：期刊文献

中文题名：静电喷雾辅助交联制备超薄复合膜及其性能研究

英文题名：Study on performance of thin-film composite membrane prepared by electrospray-assisted crosslinking method

作者：张晟宁[1];张昊[1];黄志浩[1];刘伟良[1];李文轩[1];马晓华[1]

机构：[1]化学工程国家重点实验室,华东理工大学膜科学与工程研发中心,上海200237

年份：2021

卷号：41

期号：3

起止页码：29

中文期刊名：膜科学与技术

外文期刊名：Membrane Science and Technology

收录：CSTPCD;;北大核心:【北大核心2020】；CSCD:【CSCD2021_2022】；

基金：国家自然科学基金项目(21978081)。

语种：中文

中文关键词：静电喷雾;交联;聚乙烯亚胺;超薄复合膜;染料分离

外文关键词：electrospray;crosslinking;polyethyleneimine;thin-film composite membrane;dye removal

摘要：采用静电喷雾辅助交联聚合物制备了超薄聚乙烯亚胺(PEI)/戊二醛(GA)复合膜.考察了PEI浓度、电喷雾时间等对PEI/GA复合膜物理化学性质和分离性能的影响.通过SEM、AFM、FTIR、接触角和Zeta电位对复合膜的微观形貌、交联反应、亲水性和荷电性进行了表征.选用阳离子染料通过错流装置对复合膜的分离性能进行了测试.结果表明,采用静电喷雾辅助交联法成功制备出表面均匀致密、粗糙度小、亲水性得到明显改善的荷正电的PEI/GA复合膜,该膜对阳离子染料亚甲基蓝(MLB)和结晶紫(CV)的截留率分别达到95.1%和97.5%.通过改变PEI浓度和电喷雾时间可有效调控复合膜的分离性能,以满足更广泛的应用需求.
In this paper,a thin-film polyethyleneimine(PEI)/glutaraldehyde(GA)composite membrane was prepared through electrospray-assisted crosslinking method.The effects of PEI concentration and electrospray time on the physical and chemical properties and separation performance of the PEI/GA composite membrane were studied.The microscopic morphology,crosslinking reaction,hydrophilicity and chargeability of the composite membrane were characterized by SEM,AFM,FTIR,contact angle and Zeta potential.The separation performance of the composite membrane was tested by using cationic dyes through a cross-flow device.The results showed that the positively charged PEI/GA composite membrane with uniform and compact surface,small roughness,and significantly improved hydrophilicity was successfully prepared through the electrospray-assisted crosslinking method.The rejection for the cationic dyes methylene blue(MLB)and crystal violet(CV)reached 95.1%and 97.5%,respectively.By changing the PEI concentration and electrospray time,the separation performance of the composite membrane can be effectively controlled to meet the needs of a wider range of applications.