文献类型：期刊文献

中文题名：稠环芳基取代的菲咯啉亚胺类配体在乙烯齐聚中的应用

英文题名：Application of polycyclic aryl-substituted imino-phenanthroline ligands in ethylene oligomerization

作者：隋军龙[1];刘瑶[2];赵兴[2];张军[2]

机构：[1]中石化(北京)化工研究院有限公司燕山分公司橡塑新型材料合成国家工程研究中心,北京102500;[2]华东理工大学化学与分子工程学院,上海200237

年份：2024

卷号：41

期号：5

起止页码：6

中文期刊名：合成树脂及塑料

外文期刊名：China Synthetic Resin and Plastics

收录：CSTPCD;;北大核心:【北大核心2023】；

语种：中文

中文关键词：乙烯齐聚;铁系催化剂;菲咯啉亚胺配体;线性α-烯烃;催化剂性能

外文关键词：ethylene oligomerization;iron catalyst;imino-phenanthroline ligand;linearα-olefin;catalytic performance

摘要：设计并合成了一系列稠环芳基取代的菲咯啉亚胺类配体,用于铁系催化剂催化乙烯齐聚,通过配体修饰考察了稠环芳基的位阻和电子效应对催化剂性能的影响,并考察了反应条件对催化剂性能的影响。结果表明:稠环芳基取代的菲咯啉亚胺类配体在铁系催化剂催化乙烯齐聚中性能优良,活性达13.60×10^(6) g/(mol·h),α-烯烃选择性为92%,C_(14)与C_(12)摩尔比(K值)为0.49;通过条件优化,该类催化剂活性最高能达到17.39×10^(6) g/(mol·h),α-烯烃选择性达96%,K值为0.63。
A series of imino-phenanthroline ligands bearing polycyclic aryl were synthesized and used for ethylene oligomerization over Fe catalysts.The effects of steric and electronic effect of polycyclic aryl on catalytic performance were investigated by ligand modification,and the influence of reaction conditions on catalytic behavior were studied.The results show that those polycyclic aryl-substituted phenanthroline imine ligands exhibit excellent catalytic performance in iron-catalyzed ethylene oligomerization,with an activity of up to 13.60×10^(6) g/(mol·h),an α-olefin selectivity of 92%,and a molar ratio of C_(14) to C_(12)(K-value)of 0.49.After optimization for reaction conditions,the activity of the catalysts could reach as high as 17.39×10^(6) g/(mol·h),in combination with 96% of α-olefin selectivity and the K-value of 0.63.