文献类型：期刊文献

英文题名：Concurrent destruction strategy: NaNO₂-catalyzed, trichlorophenol-coupled degradation of p-nitrophenol using molecular oxygen

作者：Fu, Dongmei[1];Peng, Yanrong[1];Liu, Renhua[2];Zhang, Feifang[1];Liang, Xinmiao[1,2]

机构：[1]Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China;[2]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2009

卷号：75

期号：6

起止页码：701

外文期刊名：CHEMOSPHERE

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000266145600001)】；

基金：We gratefully acknowledge the financial support from the grant of Key Project of Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-HO4), the National High Technology Research and Development Program of China (863 Program, No. 2008AA06Z306) and the National Science Foundation of China (No. 20707026). We thank Prof. Xiaoli Dong at the Dalian Polytechnic University for total organic carbon analysis. We also thank Prof. Lefeng Zhangand Dr. Alfyer Yediler for the correction of the manuscript.

语种：英文

外文关键词：Wet oxidation; Sodium nitrite; Wastewater treatment; Fate of carbon

摘要：Oxidative degradation of p-nitrophenol (PNP) was investigated with NaNO2 as the catalyst and dioxygen as the oxidizing agent in the presence of trichlorophenol (TCP). Although degradation of PNP alone was proved to be inefficient toward the NaNO2-mediated oxidative degradation system, when PNP in combination with TCP was used as the substrate, NaNO2 showed relatively high catalytic activity for eradicating both PNP and TCP with molecular oxygen. Reaction conditions to the degradation system, e.g., temperatures, reaction time, pH, NaNO2 and TCP concentrations were optimized. PNP could be highly efficiently degraded in the NaNO2/TCP/O-2 system (more than 99% removal for PNP) and the TOC removal of the mixture of PNP and TCP could reach 71% at 150 degrees C, 0.5 MPa oxygen pressure. Degradation products were determined, and 93% carbon atom was clarified. A plausible overall mechanism for the formation of active species is described, in which peroxylnitrite was believed to be a dominating active intermediate being responsible for destroying the substrates, PNP and TCP. The novel NaNO2-based concurrent oxidation system for PNP and TCP provides a potential application in treatment of multi-component industrial effluents. (c) 2009 Elsevier Ltd. All rights reserved.