文献类型：期刊文献

英文题名：Highly N2-Regioselective TsOH-Catalyzed Olefin Hydroamination: Metal-Free Synthesis of N2-Alkyl-1,2,3-triazoles

作者：Wei, Hao[2];Hu, Qingxia[1];Ma, Yutao[1];Wei, Liangming[2];Liu, Jiaqiang[4];Shi, Min[1,3];Wang, Feijun[1]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]Shanghai Jiao Tong Univ, Sch Elect Informat & Elect Engn, Shanghai 200240, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China;[4]Shanghai Jiao Tong Univ, Sch Med, Peoples Hosp 9, Dept Oral & Craniomaxillofacial, Shanghai 200011, Peoples R China

年份：2017

卷号：6

期号：6

起止页码：662

外文期刊名：ASIAN JOURNAL OF ORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000405134900004)，CCR-EXPANDED(收录号:WOS:000405134900004)】；

基金：We are grateful for financial support from the National Natural Science Foundation of China (21372075, 81670958 and 81371178), the Shanghai Pujiang Program (16PJD017 and 16PJD027), and the Medical-Engineering Crossover Fund of Shanghai Jiao Tong University (YG2015MS23 and YG2016MS71).

语种：英文

外文关键词：Bronsted acid catalyst; hydroamination; regioselectivity; NH-1,2,3-triazoles; organocatalysis

摘要：A highly N-2-regioselective functionalization of 2H-1,2,3-triazole and 1H-1,2,3-triazole was achieved via a para-toluenesulfonic-acid-catalyzed olefin hydroamination. The reaction afforded the corresponding products with up to 92% N-2 regioselectivity.