文献类型：期刊文献

中文题名：萜烯酚树脂与聚丙烯酸酯相容性研究

英文题名：Study on compatibility of terpene phenol resin with polyacrylate

作者：张晓晖[1];钱军[1];石一峰[2];蔡东明[3];陈远新[3]

机构：[1]华东理工大学材料科学与工程学院,上海200237;[2]上海宏顶房科技有限公司,上海200237;[3]韶关林和林产科技有限公司,广东韶关511130

年份：2025

卷号：45

期号：S2

起止页码：359

中文期刊名：现代化工

外文期刊名：Modern Chemical Industry

收录：;北大核心:【北大核心2023】；

语种：中文

中文关键词：萜烯酚树脂;丙烯酸酯压敏胶;相容性;动态力学分析

外文关键词：terpene phenol resin;acrylate pressure sensitive adhesive;compatibility;dynamic mechanical analysis

摘要：以苯酚和松节油为原料,通过调节二者比例制备了4种萜烯酚树脂;以丙烯酸异辛酯(EHA)、丙烯酸丁酯(BA)、丙烯酸甲酯(MA)为单体通过溶液聚合制备了不同的聚丙烯酸酯;将4种萜烯酚树脂分别加入不同的聚丙烯酸酯中,考察不同共混物相容性和粘接性能的差异。研究结果表明,随着苯酚用量增加,萜烯酚树脂的极性先增大后基本保持不变;极性较小的萜烯酚树脂与聚丙烯酸酯相容性更佳;萜烯酚树脂对聚丙烯酸酯的粘接性能有所提高,但是对其润湿性能有负面影响。
Four kinds of terpene phenol resins are prepared by adjusting the ratio of phenol to turpentine.Different polyacrylate are prepared via solution polymerization using 2-ethylhexyl acrylate(EHA),butyl acrylate(BA)and methyl acrylate(MA)as raw materials.Four kinds of terpene phenol resins are separately added into different polyacrylate,and the differences in compatibility and adhesion properties of different blends are studied.Study results show that the polarity of terpene phenol resin increases firstly and then remains basically unchanged with the increase of phenol dosage.The terpene phenol resin with less polarity has better compatibility with polyacrylate.The adhesion property of polyacrylate is improved due to blending with terpene phenol resin,but the wettability is negatively affected.