文献类型：期刊文献

英文题名：Synthesis of novel axially chiral Rh-NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones

作者：Duan, WL; Shi, M; Rong, GB

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Pharmaceut, Shanghai 200237, Peoples R China

年份：2003

期号：23

起止页码：2916

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000186660700034)，CCR-EXPANDED(收录号:WOS:000186660700034)】；

语种：英文

摘要：Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.