详细信息

Palladium-Catalyzed Electrochemical C-H Bromination Using NH4Br as the Brominating Reagent  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:Palladium-Catalyzed Electrochemical C-H Bromination Using NH4Br as the Brominating Reagent

作者:Yang, Qi-Liang[1,2,3];Wang, Xiang-Yang[3];Wang, Tong-Lin[3];Yang, Xiang[3];Liu, Dong[3];Tong, Xiaofeng[1,2];Wu, Xin-Yan[1,2];Mei, Tian-Sheng[3]

机构:[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organomet Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China

年份:2019

卷号:21

期号:8

起止页码:2645

外文期刊名:ORGANIC LETTERS

收录:;WOS:【SCI-EXPANDED(收录号:WOS:000465644300033),CCR-EXPANDED(收录号:WOS:000465644300033)】;

基金:This work was financially supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (grant XDB20000000), NSF of China (grants 21772222 and 21821002), and S&TCSM of Shanghai (grants 17JC1401200 and 18JC1415600).

语种:英文

摘要:The palladium-catalyzed electrochemical C-H bromination of benzamide derivatives under divided cells is developed, in which NH4Br serves as a brominating reagent and electrolyte. The protocol avoids the use of chemical oxidants and provides an alternative method for the synthesis of aryl bromides.

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