文献类型：期刊文献

中文题名：苯加氢制环己烷的反应动力学研究进展

英文题名：Advances in the Reaction Kinetics of Benzene Hydrogenation to Cyclohexane

作者：周志明[1];程振民[1];袁渭康[1]

机构：[1]华东理工大学联合化学反应工程研究所,上海200237

年份：2003

卷号：19

期号：2

起止页码：171

中文期刊名：化学反应工程与工艺

外文期刊名：Chemical Reaction Engineering and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

基金：(国家自然科学基金资助项目(N0.20106005);中国石化总公司资助项目(合同号201085)。

语种：中文

中文关键词：苯;加氢反应;环己烷;反应动力学;反应原理;热力学平衡;催化剂;催化机理

外文关键词：benzene hydrogenation;catalyst;partially wetting;reaction kinetics

摘要：　从化学反应原理、热力学平衡以及催化剂和催化机理等角度出发,详细介绍了苯加氢制环己烷的反应体系;分别就催化剂颗粒处于气相、液相和部分润湿状态下的反应动力学研究进行了概述,重点讨论了催化剂颗粒处于内部部分润湿状态下的反应动力学。
The hydrogenation of benzene to cyclohexane based on thermodynamics, the principles of chemical reactions as well as catalysts and catalytic mechanism was discussed. The reaction kinetics of benzene hydrogenation to cyclohexane was summarized in terms of the conditions of catalysts used, that is, gas phase, liquid phase and partially wetting phase. Due to its complexity and importance, the partially wetting of catalyst pellets was attracted more attentions in many researches. It was also discussed emphatically in this paper.