文献类型：期刊文献

中文题名：红外光谱法测定St-BMA的竞聚率

英文题名：Measurement of Relative Reactivity Ratios of Styrene and BMA by FTIR

作者：陆志豹[1];陈憬[1];韩哲文[1];吴平平[1]

机构：[1]华东理工大学高分子材料系

年份：1993

卷号：14

期号：10

起止页码：1473

中文期刊名：高等学校化学学报

外文期刊名：Chemical Journal of Chinese Universities

收录：CSTPCD;;Scopus;北大核心:【北大核心1992】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：竞聚率;红外光谱;苯乙烯;BMA

外文关键词：Relative reactivity ratio, FTIR, St-BMA

摘要：对于共聚合反应中同一对单体的竞聚率,由于采用的实验方法、计算方法不同,可能有几对、甚至上百对不同的数据。在实际生产中已逐渐趋向于在较高温度下进行共聚合,而文献的竞聚率一般均在较低温度下获得,因此缺乏实用意义。本文用FTIR方法测定苯乙烯（St）-甲基丙烯酸正丁酯（BMA）共聚竞聚率参数r₁和r₂,讨论了温度的影响。
For the system of styrene/n-butyl methacrylate/AIBN, copolymerizations were carried out at 40℃, 60℃ , 80℃ , 100℃ , 120℃ , 140℃ respectively. The compositions of copoly-mers were analyzed by FTIR. The relative reactivity ratios of St and BMA are calculated by the error-in variables method, and 95% joint confidence intervals of the reactivity ratios are also given. The relative reactivity ratios of St-BMA system at different temperatures were obtained from the linear relation of relative reactivity rarios and temperatures by regression treatment.