文献类型：期刊文献

英文题名：Synthesis of Chiral Bis(N-heterocyclic carbene) Palladium and Rhodium Complexes with 1,1′-Biphenyl Scaffold and Their Application in Asymmetric Catalysis

作者：Liu, Lian-jun[1,2];Wang, Feijun[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2009

卷号：28

期号：15

起止页码：4416

外文期刊名：ORGANOMETALLICS

收录：;EI(收录号：20093312250061);WOS:【SCI-EXPANDED(收录号:WOS:000268455900027)】；

语种：英文

外文关键词：Synthesis (chemical) - Catalyst activity - Crystal structure - Ketones - Palladium compounds - Hydrosilylation - Metal complexes - Rhodium compounds

摘要：Axially chiral bis(NFIC) Pd(II) and Rh(III) complexes with 1,1'-biphenyl scaffold have been successfully synthesized from the corresponding chiral 6,6'-dimethoxybiphenyl-2-2'-diamine. These interesting NFIC-metal complexes have been characterized by X-ray crystal structure diffraction. When applied in the oxidative kinetic resolution of sec-alcohols and hydrosilylation of ketones, these catalysts showed good catalytic activities with moderate to high enantioselectivities.