文献类型：期刊文献

英文题名：Improvement of the oxidation resistance of silicon-containing arylacetylene resins upon the introduction of carbazoles

作者：Wan, Ling[1];Guo, Kangkang[1,2];Zhu, Junli[2];Wang, Fan[1];Zhu, Yaping[1];Deng, Shifeng[1];Qi, Huimin[1]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Specially Funct Polymer Mat & Related Tec, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Shanghai Key Lab Adv Polymer Mat, Shanghai, Peoples R China

年份：2021

卷号：138

期号：1

外文期刊名：JOURNAL OF APPLIED POLYMER SCIENCE

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000552098900001)】；

基金：This work was supported by the Fundamental Research Funds for the Central Universities (5032104918013 and 5032104917001).

语种：英文

外文关键词：differential scanning calorimetry (DSC); thermal properties; thermogravimetric analysis (TGA); crosslinking; copolymers

摘要：Silicon-containing arylacetylene resins (PSAs) can be used in high temperature environment due to their excellent thermal stability. However, their high temperature oxidation is still bottle-neck for further application. Herein, Materials Genome Initiative (MGI) was utilized to identify a target monomer, 3,6-diethynylcarbazole (DEC), to design new PSAs with enhanced antioxidant properties and heat resistance. After incorporation of DEC, the thermal curing behavior observed using differential scanning calorimetry (DSC), fourier transform infrared (FTIR) and thermogravimetric analysis (TGA) revealed that obtained silicon-containing carbazolylacetylene resins (PSA-VBC) can exhibit hydroamination reaction to decrease the initial curing temperature. And the temperature at 5% weight loss (T-d5) occurred in cured copolymers ranged from 665 degrees C to 691 degrees C, which showed excellent heat resistance. Moreover, the oxidation behavior of cured resins was investigated by thermogravimetric/derivative thermogravimetry (TG/DTG), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM). Upon the incorporation of DEC, the thermal oxidation decomposition temperature of PSA-VBC were 100 degrees C higher than those observed for PSAs, which also proved by XPS analysis results that the oxygen content of PSA-VBC solidified oxide was lower than that of PSAs. In addition, the surface morphology of cured PSA-VBC resins still maintained integrity after oxidation at 400 degrees C for 2 hr, which showed excellent oxidation resistance.