文献类型：期刊文献

英文题名：Bifunctional chiral phosphine-containing Lewis base catalyzed asymmetric Morita-Baylis-Hiliman reaction of aldehydes with activated alkenes

作者：Lei, Zhi-Yu[1,2];Liu, Xu-Guang[1,2];Shi, Min[1,2,3];Zhao, Meixin[1,2]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

年份：2008

卷号：19

期号：17

起止页码：2058

外文期刊名：TETRAHEDRON-ASYMMETRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000260081900010)，CCR-EXPANDED(收录号:WOS:000260081900010)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (04JC14083, 06XD14005), and the National Natural Science Foundation of China for financial support (20472096, 203900502, 20672127, 20772030 and 20732008).

语种：英文

摘要：A series of novel bifunctional chiral phosphine-containing Lewis bases were synthesized and successfully applied to the asymmetric Morita-Baylis-Hillman reaction of alclehydes with methyl vinyl ketone (MVK) and ethyl vinyl ketone (EVK) to give the corresponding adducts in moderate yields and enantioselectivities under mild reaction conditions. (C) 2008 Elsevier Ltd. All Fights reserved.