文献类型：期刊文献

英文题名：STUDY OF CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS .1. EXPERIMENTAL-MEASUREMENT OF CHEMICAL-EQUILIBRIUM COMPOSITION AND CONSTANT KP

作者：LIU, H; LUO, ZC; ZHU, BC

机构：[1]E CHINA UNIV SCI & TECHNOL,DEPT CHEM ENGN,SHANGHAI 200287,PEOPLES R CHINA

年份：1994

卷号：12

期号：6

起止页码：815

外文期刊名：FUEL SCIENCE & TECHNOLOGY INTERNATIONAL

收录：;WOS:【SCI-EXPANDED(收录号:WOS:A1994NJ60600001)】；

语种：英文

摘要：The chemical equilibrium compositions and equilibrium constants of methanol synthesis reactions, starting from carbon monoxide, carbon dioxide and hydrogen, were studied experimentally at P=4.0-6.6MPa and t=220 approximately 260-degrees-C. It was found that lower temperatures and higher pressures are favourable to chemical equilibria in the interested range of the synthesis reactions using low-pressure process, but the influence of temperature on K(P) is much larger than that of pressure.