文献类型：期刊文献

英文题名：The Advance and Application of Rare Earth Perfluorooctanoate [RE(PFO)₃]

作者：Tang, Jun;Wang, Limin[1];Wu, Shengying;Mao, Dan

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2011

期号：20

起止页码：2913

外文期刊名：SYNLETT

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000298155800002)】；

基金：This research was financially supported by the National Nature Science Foundation of China (20672035) and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：rare earths; perfluorooctanoate; multicomponent condensation reaction; Lewis acids; homogeneous catalysis

摘要：Synthesis and characterization of a new type of Lewis acid, rare earth metal perfluorooctanoate, as well as the recent development of multicomponent condensation reactions catalyzed by rare earth metal perfluorooctanoate has been introduced. 1 Introduction and Background 2 Synthesis and Characterization of Rare Earth Perfluorooctanoate 2.1 Synthesis of Rare Earth Perfluorooctanoate 2.2 Characterization of Rare Earth Perfluorooctanoate 3 RE(PFO)(3) in Organic Solvent 3.1 One-Pot Mannich Reaction 3.2 Condensations of Indole with Carbonyl Compounds 3.3 One-Pot Synthesis of Benzopyran Derivatives 3.4 One-Pot Synthesis of 2-Amino-3-Cyanopyridine Derivatives 4 RE(PFO)(3) in Water 4.1 Doebner Reaction 4.2 Synthesis of Homoallylic Alcohols and Amines 5 RE(PFO)(3) under Solvent-Free Conditions 5.1 Synthesis of alpha-Aminophosphonates 5.2 One-Pot Synthesis of Substituted Pyrazoles 5.3 A Revisit to the Hantzsch Reaction 5.4 One-Pot Fluorous Biginelli Reaction 6 Summary