文献类型：期刊文献

英文题名：p-Toluenesulfonic acid-promoted autocatalytic hydrolyzation of 1-tosyl-1,2,3-triazoles

作者：Dong, Haohao[1];Zhang, Dongdong[1];Fang, Renjie[1];Du, Qingyang[1];Dong, Zhuoya[1];Wei, Hao[2];Shi, Min[1,3];Wang, Feijun[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]Shanghai Jiao Tong Univ, Minist Educ, Sch Elect Informat & Elect Engn, Key Lab Thin Film & Microfabricat Technol, 800 Dongchuan Rd, Shanghai 200240, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai, Peoples R China

年份：2018

卷号：48

期号：10

起止页码：1227

外文期刊名：SYNTHETIC COMMUNICATIONS

收录：;EI(收录号：20242616435723);WOS:【SCI-EXPANDED(收录号:WOS:000432219600012)，CCR-EXPANDED(收录号:WOS:000432219600012)】；

语种：英文

外文关键词：1,2,3-Triazoles; autocatalytic hydrolyzation; brOnsted acid

摘要：The first example of autocatalytic hydrolyzation of 4-aryl-1-tosyl-1,2,3-triazoles induced by p-toluenesulfonic acid was reported, providing an effective and metal-free synthetic approach to deliver a broad range of new 4-aryl-2H-1,2,3-triazoles in good yields. The kinetic profile of this hydrolyzation suggested that this reaction has exponential autocatalytic behavior. [GRAPHICS] .