文献类型：期刊文献

中文题名：氨基硫脲Schiff碱的合成和X-射线粉末衍射数据的指标化

英文题名：STUDIES ON THE SYNTHESIS OF THIOSEMICARBAZONE Schiff BASE AND INDICES OF X-RAY POWDER DIFFRACTION PATTERN

作者：郭应臣[1];钟国清[2];栾绍嵘[3];卓立宏[1]

机构：[1]南阳师范学院化学系,湖南南阳473061;[2]四川畜牧兽医学院基础部,重庆402460;[3]华东理工大学化学系,上海200237

年份：2001

卷号：13

期号：4

起止页码：430

中文期刊名：化学研究与应用

外文期刊名：Chemical Research and Application

收录：CSTPCD;;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：D(+)-葡萄糖;氨基硫脲;Schiff碱;X射线粉末衍射;指标化;合成;西佛碱;衍射数据;结构

外文关键词：D(+) glucose;thiosemicarbazone;Schiff base;X ray powder diffraction;index

摘要：D(+) glucose thiosemicarbazone(Ⅰ) and salicylaldehyde thiosemicarbazone(Ⅱ) are synthesized.The compositions and structures of the compounds have been characterized by the elemental analysis,UV spectra, 1H NMR graph,IR spectra and X ray powder diffraction.The results of indexes to the X ray powder diffraction patterns indicate that the crystal structures of the two compounds belong to triclinic system,(Ⅰ) with a=0.5776nm,b=0.7372nm,c=1.5933nm,α=91.35°,β=94.15°,γ=94.67°, V =0.6741nm 3,Z=2, D cal =1.248g·cm -3 ;(Ⅱ):a=0.7223nm,b=1.0943nm,c=2.8834nm,α=84.16°,β=89.75°,γ=98.38°, V =2.2425nm 3,Z=8, D cal =1.157g·cm -3 .
D(+) glucose thiosemicarbazone(Ⅰ) and salicylaldehyde thiosemicarbazone(Ⅱ) are synthesized.The compositions and structures of the compounds have been characterized by the elemental analysis,UV spectra, 1H NMR graph,IR spectra and X ray powder diffraction.The results of indexes to the X ray powder diffraction patterns indicate that the crystal structures of the two compounds belong to triclinic system,(Ⅰ) with a=0.5776nm,b=0.7372nm,c=1.5933nm,α=91.35°,β=94.15°,γ=94.67°, V =0.6741nm 3,Z=2, D cal =1.248g·cm -3 ;(Ⅱ):a=0.7223nm,b=1.0943nm,c=2.8834nm,α=84.16°,β=89.75°,γ=98.38°, V =2.2425nm 3,Z=8, D cal =1.157g·cm -3 .