文献类型：期刊文献

英文题名：Carbon mediated catalysis: A review on oxidative dehydrogenation

作者：Chen, De[1];Holmen, Anders[1];Sui, Zhijun[2];Zhou, Xinggui[2]

机构：[1]Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway;[2]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2014

卷号：35

期号：6

起止页码：824

外文期刊名：CHINESE JOURNAL OF CATALYSIS

收录：;EI(收录号：20142617856453);WOS:【SCI-EXPANDED(收录号:WOS:000337120600008)】；

基金：The financial supports from the Norwegian Research Council, the 111 299 Project of Ministry of Education of China (B08021), and the European Commission FP-7 Project FREECATS (Grant agreement no.: 280658) are gratefully acknowledged.

语种：英文

外文关键词：Oxidative dehydrogenation; Carbon mediated catalysis; Carbon nanomaterial; Ethylbenzene

摘要：Carbon mediated catalysis has gained an increasing attention in both areas of nanocatalysis and nanomaterials. The progress in carbon nanomaterials provides many new opportunities to manipulate the types and properties of active sites of catalysts through manipulating structures, functionalities and properties of carbon surfaces. The present review focuses on progresses in carbon mediated oxidative dehydrogenation reactions of ethylbenzene, propane, and butane. The state-of-the-art of the developments of carbon mediated catalysis is discussed in terms of fundamental studies on adsorption of oxygen and hydrocarbons, reaction mechanism as well as effects of carbon nanomaterial structures and surface functional groups on the catalytic performance. We highlight the importance and challenges in tuning of the electron density of carbon and oxygen on carbon surfaces for improving selectivity in oxidative dehydrogenation reactions. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.