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New π-conjugated cyanostilbene derivatives:Synthesis,characterization and aggregation-induced emission    

文献类型:期刊文献

中文题名:Newπ-conjugated cyanostilbene derivatives:Synthesis,characterization and aggregation-induced emission

英文题名:New π-conjugated cyanostilbene derivatives:Synthesis,characterization and aggregation-induced emission

作者:Fang Wang[1,2];Xue Li[1,2];Sheng Wang[1,2];Cheng-Peng Li[2];Huan Dong[3];Xiang Ma[3];Sung-Hoon Kim[4];De-Rong Cao[1]

机构:[1]School of Chemistry and Chemical Engineering,State Key Laboratory of Luminescent Materials and Devices,South China University of Technology.Cuangzhou 510641,China;[2]Key Laboratory of Applied Chemistry and School of Chemistry and Chemical Engineering,Development Center for New Materials Engineering&Technologyin Universities of Guangdong,Lingnan Normal University,Zhanjiang 524048,China;[3]Key Laboratory for Advanced Materials and Institute of Fine Chemicals,East China University of Science and Technology,Shanghai 200237,China;[4]Department of Advanced Organic Materials Science and Engineering,Kyungpook National University,Daegu 702-701,Republic of Korea

年份:2016

卷号:27

期号:10

起止页码:1592

中文期刊名:Chinese Chemical Letters

外文期刊名:中国化学快报(英文版)

收录:CSTPCD;;Scopus;CSCD:【CSCD2015_2016】;PubMed;

基金:financially supported by NSFC(Nos.21372194,21476075 and 21272072);the Guangdong Yangfan Talent Plan(2013);the Research Funds of Lingnan Normal University(No.QL1402)

语种:英文

中文关键词:π-Conjugated cyanostilbene derivatives1;4-Dihydropyrro[3;2-b]indoleTetraphenylethyleneAggregation-induced emissionMaterials Studio

外文关键词:π-Conjugated cyanostilbene derivatives1,4-Dihydropyrro[3,2-b]indoleTetraphenylethyleneAggregation-induced emissionMaterials Studio

摘要:Two novel Jr-conjugated cyanostilbene derivatives, FLU-CNPH and TPE-CNPH, were designed aria synthesized by introducing the strong electron donor 1, 4-dihydropyrro[3,2-b]indole and AIE electron donor tetraphenylethylene (TPE) to the (3',5'-bis(trifluoromethyl)-biphenyl-4-yl)-acetonitrile, respec- tively, Both of them were fully characterized and their AIE behaviors were investigated using fluorescence spectroscopy and FE-SEM images. Their optimized structures and frontier molecular orbitals were calculated with the DFT by using Materials Studio 7,0 software to study the relationship between the structure and properties.
Two novel Jr-conjugated cyanostilbene derivatives, FLU-CNPH and TPE-CNPH, were designed aria synthesized by introducing the strong electron donor 1, 4-dihydropyrro[3,2-b]indole and AIE electron donor tetraphenylethylene (TPE) to the (3',5'-bis(trifluoromethyl)-biphenyl-4-yl)-acetonitrile, respec- tively, Both of them were fully characterized and their AIE behaviors were investigated using fluorescence spectroscopy and FE-SEM images. Their optimized structures and frontier molecular orbitals were calculated with the DFT by using Materials Studio 7,0 software to study the relationship between the structure and properties.

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