文献类型：期刊文献

中文题名：煤焦油和石油基柴油馏分中含氮化合物的分离鉴定

英文题名：SEPARATION AND IDENTIFICATION OF NITROGEN COMPOUNDS IN DIESEL FRACTION OF COAL TAR AND PETROLEUM

作者：杨敬一[1];周秀欢[1];蔡海军[2];王红晨[2]

机构：[1]华东理工大学化工学院,上海200237;[2]中国石油乌鲁木齐石化公司

年份：2015

卷号：46

期号：7

起止页码：107

中文期刊名：石油炼制与化工

外文期刊名：Petroleum Processing and Petrochemicals

收录：CSTPCD;;Scopus;北大核心:【北大核心2014】；CSCD:【CSCD_E2015_2016】；

语种：中文

中文关键词：含氮化合物;煤焦油;催化裂化柴油;直馏柴油;焦化柴油;GC/MS

外文关键词：nitrogen compound; coal tar; FCC diesel; straight-run diesel; coking diesel; GC/MS

摘要：对两种煤焦油柴油馏分和石油基催化裂化柴油、焦化柴油、直馏柴油中的含氮化合物进行了鉴定分析。采用硅胶柱分离富集5种柴油中的非碱性含氮化合物,酸萃取法萃取碱性含氮化合物,利用GC/MS分离定性。结果表明:煤焦油柴油馏分中非碱性含氮化合物主要是咔唑和吲哚类化合物,碱性含氮化合物以喹啉、吡啶和苯胺类为主;催化裂化柴油以咔唑和吲哚类非碱性含氮化合物为主;焦化柴油以吡啶和喹啉类碱性含氮化合物为主;直馏柴油中主要是咔唑类非碱性含氮化合物,还有少量的喹啉和苯胺类碱性含氮化合物。煤焦油柴油馏分和焦化柴油以碱性含氮化合物为主,催化裂化柴油和直馏柴油以非碱性含氮化合物为主,煤焦油柴油馏分中的碱性含氮化合物种类及含量远高于石油馏分。
In this paper, nitrogen compounds in two kinds of coal tar diesel fraction and three kinds of diesel（FCC diesel, coking diesel and straight-run diesel）were separated and identified. The non-basic nitrogen compounds was separated by silicagel column and the basic nitrogen compounds was extracted from diesel by HCL, then the separated nitrogen compounds were identified by using GC/MS. The results show that in two coal tar diesel fractions, non-basic nitrogen compounds including carbazole and indole as well as basic nitrogen compounds including quinoline, pyridine and aniline are the main nitro- gen compounds. The basic nitrogen compounds including pyridine and quinoline are given priority in co- king diesel. Straight-run diesel mainly contains non-basic nitrogen compounds including carbazole and a small amount of basic nitrogen compounds including quinoline and aniline. The basic nitrogen corn pounds are mainly in coal tar diesel fraction and coking diesel, and the non-basic nitrogen compounds are mainly in FCC diesel and straight-run diesel. The kinds and amount of basic nitrogen compounds in coal tar diesel is much more than that in petroleum diesel.