文献类型：期刊文献

英文题名：Fluoroalkylation of pent-4-en-1-ols initiated by sodium dithionite to synthesize fluorine-containing tetrahydrofuran derivatives

作者：Yang, Xueyan; Wang, Zhonghua; Zhu, Yaoping; Fang, Xiang; Yang, Xianjin; Wu, Fanhong; Shen, Yongjia

机构：[1]E China Univ Sci & Technol, Inst Fine Chem, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organoflourine Chem, Shanghai 200032, Peoples R China

年份：2007

卷号：128

期号：9

起止页码：1046

外文期刊名：JOURNAL OF FLUORINE CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000249413300009)】；

语种：英文

外文关键词：addition; cyclization; fluorine-containing; tetrahydrofuran

摘要：Fluoroalkylation of pent-4-en-1-ols with RCF2I initiated by Na2S2O4 was carried out at 5-10 degrees C in aqueous acetonitrile affording corresponding adducts, which were converted to fluoroalkyl tetrahydrofurans by heating in DMF or acetonitrile, providing a convenient method for the synthesis of fluorine-containing tetrahydrofuran derivatives. (c) 2007 Published by Elsevier B.V.