文献类型：期刊文献

英文题名：A Pd(II)-catalyzed asymmetric approach toward chiral [3.3.1]-bicyclic ketals using 2-hydroxyphenylboronic acid as a pro-bis(nucleophile)

作者：Wang, Feijun[1,2];Chen, Feng[1,2];Qu, Mingliang[1,2];Li, Teng[1,2];Liu, Yunlong[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

年份：2013

卷号：49

期号：32

起止页码：3360

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000316693100026)，CCR-EXPANDED(收录号:WOS:000316693100026)】；

基金：Financial support from the Shanghai Municipal Committee of Science and Technology (11JC1402600), the National Natural Science Foundation of China (21072206, 20902019, 20472096, 20872162, 20672127, 21121062 and 20732008), the National Basic Research Program of China (973)-2010CB833302, and the Fundamental Research Funds for the Central Universities is gratefully acknowledged.

语种：英文

摘要：Enantioselective Pd(II)-catalyzed construction of [3.3.1]-bicyclic ketals from 2-hydroxyphenylboronic acid 1 and enone 3 is reported, yielding enantioenriched [3.3.1]-bicyclic ketals in up to 97% yields and 98% ee.