文献类型：期刊文献

中文题名：催化裂化汽油脱硫助剂的研究

英文题名：Study on the additive for desulfurization in FCC gasoline

作者：肖莉[1];边建东[1];王昕[1];施力[1]

机构：[1]华东理工大学化工学院,上海200237

年份：2007

卷号：35

期号：1

起止页码：113

中文期刊名：燃料化学学报

外文期刊名：Journal of Fuel Chemistry and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2004】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：流化催化裂化;汽油;噻吩;脱硫;助剂;溶胶凝胶

外文关键词：fluid catalytic cracking ; gasoline; thiophene; desulphurization; additive; solgel

摘要：The activity of FCC additives of Zn(Al2O)2 with different ZnO contents were prepared by solgel,and the desulfurization effect of additives in the gasoline was evaluated in a micro reactor.The results indicate that the additive with 10% ZnO shows the best desulfurization activity,the conversion of thiophene reaches 12.7%.The activity of the additives with CeO2 was also studied,which can remove 18.13% thiophene from gasoline in the micro reactor.The crystals and acidic of additives were studied by XRD and Infrared Ray.IR results show that weak Lewis acid amounts affected activity of the additives.XRD results indicate that the best crystal of Zn(Al2O)2 spinel is not in favor of removal of thiophene.When the crystallinity is low,there are more active sites with more adsorption activity.The additives show the better desulfurization effects when the adsorption sites and L acid sites reach balance.
The activity of FCC additives of Zn （Al2O）2 with different ZnO contents were prepared by solgel, and the desulfurization effect of additives in the gasoline was evaluated in a micro reactor. The results indicate that the additive with 10% ZnO shows the best desulfurization activity, the conversion of thiophene reaches 12.7%. The activity of the additives with CeO2 was also studied, which can remove 18.13% thiophene from gasoline in the micro reactor. The crystals and acidic of additives were studied by XRD and Infrared Ray. IR results show that weak Lewis acid amounts affected activity of the additives. XRD results indicate that the best crystal of Zn（Al2O）2 spinel is not in favor of removal of thiophene. When the crystallinity is low, there are more active sites with more adsorption activity. The additives show the better desulfurization effects when the adsorption sites and L acid sites reach balance.