文献类型：期刊文献

中文题名：全氟丁基取代醇、酮和烯烃的制备

英文题名：Preparation of Perfluorobutyl Substituted Alcohols,Ketones and Alkenes

作者：荣国斌[1]

机构：[1]华东理工大学化学系

年份：1996

卷号：22

期号：3

起止页码：356

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;国家哲学社会科学学术期刊数据库;Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：全氟丁基化;醇;酮;合成;烯烃

外文关键词：perfluorobutylated;alcohols;ketones;olefins;synthesis

摘要：全氟丁基锂与醛、酮、酰氯和酯反应生成全氟丁基取代醇和酮。在超声作用下，全氟丁基碘与镁作用后也可与醛或酮反应。以全氟丁基取代叔醇的脱水和全氟丁基取代仲（叔）醇的乙酸酯热解后得到全氟丁基取代烯烃。
A series of perfluorobutyl substituted alcohols and ketones were prepared by nucleophilic addition of carbonyl compounds by C_4F_9I with C_4H_9 Li or with Mg under ultrasonic irradiation.The perfluorobutylated olefins were produced via dehydration of the perfluorobutylated tertiary alcohols and by flash pyrolysis of the acetates of the corresponding perfluorobutyled secondary or tertiary alcohols.