文献类型：期刊文献

中文题名：含硫含酸原油加工中含油污水的形成与破乳研究

英文题名：Formation and Demulsification of Emulsion during Processing of Sour and Acidic Crude Oil in Refinery

作者：兰建义[1];杨敬一[1];徐心茹[1]

机构：[1]华东理工大学石油加工研究所,上海200237

年份：2010

卷号：33

期号：12

起止页码：120

中文期刊名：环境科学与技术

外文期刊名：Environmental Science & Technology

收录：CSTPCD;;北大核心:【北大核心2008】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：原油;含硫;环烷酸;脂肪酸;破乳

外文关键词：crude oil; sour; naphthenic acid; fatty acid; demulsification;

摘要：针对含硫含酸原油加工中形成的含油污水,应用红外及核磁共振对含油污水萃取物进行了表征,表明含油污水中含有石油酸类、酚类、硫化物等。乳化实验结果表明:对含油污水的乳化程度为:十二酸钠>邻甲酚钠>噻吩,石油酸类的乳化能力明显高于酚类和硫化物;脂肪酸的乳化能力高于环烷酸,随着碳链的增长脂肪酸的乳化能力增强。在缓蚀剂存在的条件下破乳剂没有降低对含油污水的破乳作用。破乳剂中Y系列破乳剂效果较好,其中YZM与XYY复配的破乳效果显著,在加剂量为10mg/L、温度为40℃、沉降时间为20min、初始油含量为10050mg/L时,破乳后水中油含量降至285.2mg/L,脱油率为97.2%;初始油含量为2100mg/L,破乳后水中油含量降至97.23mg/L,脱油率为95.4%。
The formation and demulsification of oil-in-water emulsion during processing of crude oil which contains sulfur and acid in refinery were studied. IR and H-NMR results indicated that there are petroleum acid,phenol and sulphide in the emulsion. The emulsification degree for oil-contaminated water is ranked as lauric acid sodium,orthocresol sodium and thiophene,with emulsive competence of fatty acid higher than naphthenic acid in petroleum acid,and much higher with length increase of carbon chain of fatty ac...