文献类型：期刊文献

中文题名：反应条件对生物质焦气化反应动力学的影响

英文题名：Influence of Reaction Conditions on Gasification Kinetics of Biomass Char

作者：吴亭亭[1];曹建勤[1];魏敦崧[2];闻望[2]

机构：[1]华东理工大学能源化工系;[2]同济大学热能工程系

年份：1998

卷号：24

期号：5

起止页码：559

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;国家哲学社会科学学术期刊数据库;Scopus;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金

语种：中文

中文关键词：生物质;反应条件;气化动力学;城市垃圾;废物处理

外文关键词：biomass; temperature programmed TG; reaction condition; gasification kinetics

摘要：用程序升温热重法对几种生物质的焦样进行空气气化研究，考察了升温速率、气化剂流量等因素对ＴＧ／ＤＴＧ谱图的影响。用Ｃｏａｔｓ积分法对曲线进行动力学计算，并对结果进行讨论。结果表明：ＤＴＧ参数（Ｔｍ和Ｒｍ）均随升温速率的增高而增大，表观活化能Ｅ和指前因子Ａ间存在动力学补偿效应。
Several kinds of biomass char were gasified in air, using temperature programmed thermogravimetry method. The effects of reaction conditions, such as heating rate, gasifier's current and so on, on the TG/DTG profiles were determined. The DTG parameters and kinetic parameters were calculated by Coats method. It was showed that the DTG parameters ( T m and R m) increased linearly with heating rate. From the results it could be found that there was a “Kinetic Compensation Effect”, and it had the linear relationship: lg A=0.10E -3.71.