文献类型：期刊文献

英文题名：Reactions of vinylidenecyclopropanes with diphenyl diselenide in the presence of AIBN and further transformation to produce new naphthalene derivatives

作者：Shi, Min[1,2]; Lu, Jian-Mei[1]

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Shanghai 200237, Peoples R China

年份：2006

卷号：71

期号：5

起止页码：1920

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：2006109751143);WOS:【SCI-EXPANDED(收录号:WOS:000235896800019)】；

语种：英文

外文关键词：Derivatives - Hydrogen peroxide - Naphthalene - Reaction kinetics

摘要：The reactions of vinylidencyclopropanes 1 with diphenyl diselenide 2 in the presence of AIBN produced the corresponding products 4 or 5 in moderate to good yields under mild conditions. The transformation of 4 to the corresponding methylenecyclopropanes 6 was achieved by treatment with hydrogen peroxide (H2O2) in toluene, and these were further transformed to the corresponding naphthalene derivatives 7 by treatment with 30 mot % of TfOH in dichloromethane.