文献类型：期刊文献

中文题名：Ethylenediamine： A Highly Effective Catalyst for One-Pot Synthesis of Aryl Nitroalkenes via Henry Reaction and Dehydration

英文题名：Ethylenediamine： A Highly Effective Catalyst for One-Pot Synthesis of Aryl Nitroalkenes via Henry Reaction and Dehydration

作者：Yang Jianxin Dong Jing Lu Xia Zhang Qiang Ding Wei Shi Xiaoxin[1]

机构：[1]Department of Pharmaceutical Engineering, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China

年份：2012

卷号：30

期号：12

起止页码：2827

中文期刊名：Chinese Journal of Chemistry

外文期刊名：中国化学（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2011_2012】；

基金：the National Natural Science Foundation of China （No. 20972048） and Shanghai Educational Development Foundation （The Dawn Program： No. 03SG27） for the financial support of this work.

语种：英文

中文关键词：ethylenediamine; nitroalkene; nitromethane; nitroethane; aryl aldehyde

外文关键词：ethylenediamine; nitroalkene; nitromethane; nitroethane; aryl aldehyde

摘要：Ethylenediamine （H2NCH2CHeNH2） was found to be a highly effective catalyst for the condensation of aryl aldehydes with nitromethane （or nitroethane）. When 1%-2% （tool%） of ethylenediamine was used as the catalyst, the one-pot reaction of aryl aldehydes with nitromethane （or nitroethane） by refluxing for 3-10 h efficiently afforded various arylnitroalkenes la-ly in 85%-97% yields.
Ethylenediamine （H2NCH2CHeNH2） was found to be a highly effective catalyst for the condensation of aryl aldehydes with nitromethane （or nitroethane）. When 1%-2% （tool%） of ethylenediamine was used as the catalyst, the one-pot reaction of aryl aldehydes with nitromethane （or nitroethane） by refluxing for 3-10 h efficiently afforded various arylnitroalkenes la-ly in 85%-97% yields.