文献类型：期刊文献

英文题名：Palladium-catalyzed asymmetric addition of diarylphosphines to N-tosylimines

作者：Huang, Miao[1];Li, Chun[1];Huang, Jian[1];Duan, Wei-Liang[2];Xu, Sheng[1]

机构：[1]E China Univ Chem Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

年份：2012

卷号：48

期号：90

起止页码：11148

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000309918000028)，CCR-EXPANDED(收录号:WOS:000309918000028)】；

基金：The NSFC (20902099, 21172238), National Basic Research Program of China (973 Program 2010CB833300), and SIOC are greatly acknowledged for funding this work.

语种：英文

摘要：Bis(phosphine) pincer-Pd complex-catalyzed asymmetric addition of diarylphosphines to N-tosylimines was developed for the synthesis of chiral phosphine sulfides with high stereoselectivities (up to 96% ee) under mild conditions.