文献类型：期刊文献

英文题名：Metal free access to amide compounds via peroxide-mediated N=N double bond cleavage of azobenzenes

作者：Hong, Gang[1];Mao, Dan;Zhu, Xiaoyan;Wu, Shengying;Wang, Limin

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2015

卷号：2

期号：8

起止页码：985

外文期刊名：ORGANIC CHEMISTRY FRONTIERS

收录：;EI(收录号：20184806136193);WOS:【SCI-EXPANDED(收录号:WOS:000364449200018)】；

基金：This research was financially supported by the National Nature Science Foundation of China (21272069, 20672035) and the Fundamental Research Funds for the Central Universities and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：Amides

摘要：A direct amidation of aldehydes or benzylamines with azobenzenes through TBHP-mediated N=N double bond cleavage of azobenzenes has been developed. A series of amide compounds with a wide range of functionalities were obtained with moderate to good yields. To the best of our knowledge, this is the first example of the N=N double bond cleavage of azobenzenes used in synthesizing amide compounds.