文献类型：期刊文献

英文题名：From Precision Synthesis of Block Copolymers to Properties and Applications of Nanoparticles

作者：Li, Xiao[1,2,3];Iocozzia, James[3];Chen, Yihuang[3];Zhao, Shiqiang[3];Cui, Xun[3];Wang, Wei[3,4];Yu, Haifeng[1,2];Lin, Shaoliang[4];Lin, Zhiqun[3]

机构：[1]Peking Univ, Minist Educ, Dept Mat Sci & Engn, Beijing 100871, Peoples R China;[2]Peking Univ, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China;[3]Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA;[4]East China Univ Sci & Technol, Key Lab Ultrafine Mat, Sch Mat Sci & Engn, Minist Educ,Shanghai Key Lab Adv Polymer Mat, Shanghai 200237, Peoples R China

年份：2018

卷号：57

期号：8

起止页码：2046

外文期刊名：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

收录：;EI(收录号：20180404668860);WOS:【SCI-EXPANDED(收录号:WOS:000424879400005)】；

基金：This work was supported by the National Natural Science Foundation of China (grant nos. 51322301, 51622301, 51573046, and 61728403), the Air Force Office of Scientific Research (FA9550-16-1-0187), and the National Science Foundation (CMMI 1562075, CMMI 172313, and DMR 1709420). X.L. gratefully acknowledges financial support from the China Scholarship Council.

语种：英文

外文关键词：core-shell structures; linear block copolymers; nanoparticles; nanoreactors; star-shaped block-copolymers

摘要：Inorganic nanoparticles have become a research focus in numerous fields because of their unique properties that distinguish them from their bulk counterparts. Controlling the size and shape of nanoparticles is an essential aspect of nanoparticle synthesis. Preparing inorganic nanoparticles by using block copolymer templates is one of the most reliable routes for tuning the size and shape of nanoparticles with a high degree of precision. In this Review, we discuss recent progress in the design of block copolymer templates for crafting spherical inorganic nanoparticles including compact, hollow, and core-shell varieties. The templates are divided into two categories: micelles self-assembled from linear block copolymers and unimolecular star-shaped block copolymers. The precise control over the size and morphology of nanoparticles is highlighted as well as the useful properties and applications of such inorganic nanoparticles.