文献类型：期刊文献

中文题名：双(1,1′-苯并三唑)-α,ω-二酰胺的合成及其缓蚀作用

英文题名：Synthesis of bis (1,1′ Benzotriazoyl) α,ω Dicarboxamides Compounds and Their Corrosion Inhibition Performance

作者：张大全[1];陆柱[1]

机构：[1]华东理工大学防腐蚀中心

年份：1999

卷号：25

期号：2

起止页码：212

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：铜;缓蚀剂;合成;苯并三唑衍生物;缓蚀作用

外文关键词：copper corrosion inhibitor;synthesis;benzotriazole derivatives;dimer;inhibition

摘要：合成了４个以—ＮＨＣＯ（ＣＨ２）ｎＣＯＮＨ—链连接的双（１，１′－苯并三唑－α，ω－二酰胺化合物（ｎ＝２，４，７，８），用红外光谱和核磁共振氢谱对其结构进行了表征。采用挂片失重法初步评价了它们在０．５ｍｏｌ／ＬＨ２ＳＯ４溶液中对铜的缓蚀作用，并用ＭＭ２分子力学程序讨论了缓蚀作用与分子结构的关系。
Four kinds of bis (1,1′ benzotriazoly) α,ω dicarboxamides compounds linked via-NHCO(CH 2) n CONH- chain: bis (1,1′ benzotriazoyl) α,ω succinylamide (BBT1), bis (1,1′ benzotriazoyl] α,ω adipoylamide (BBT2), bis (1,1′ benzotriazoyl) α,ω azelaoylamide (BBT3), bis (1,1′ benzotriazoly) α,ω decoyldiamide(BBT4) were synthesized and certified by IR and 1H NMR.Their corrosion inhibition effects for copper in 0.5 mol/L H 2SO 4 solution were evaluated by weight loss method.It shows that among these four compounds,only BBT1 has better pretection compared with BTA.The minimum energy conformation of these compounds were obtained by MM2 forcefield program.The two benzotriazole moiety in BBT1 molecule are more planar than that in other compounds.This would be benefit to increase the inhibition effects of BBT1.