文献类型：期刊文献

中文题名：Transforming bulk alkenes and alkynes into fine chemicals enabled by single-atom site catalysis

作者：Ping Guo[1];Hongyuan Liu[1];Jie Zhao[1,2]

机构：[1]Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering,Feringa Nobel Prize Scientist Joint Research Center,Frontiers Science Center for Materiobiology and Dynamic Chemistry,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237,China;[2]Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology(Ministry of Education),Department of Chemistry,Tsinghua University,Beijing 100084,China

年份：2022

卷号：15

期号：9

起止页码：7840

中文期刊名：Nano Research

外文期刊名：纳米研究（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2021_2022】；PubMed;

基金：J.Z.acknowledges Project supported by Shanghai Municipal Science and Technology Major Project(No.2018SHZDZX03);the Program of Introducing Talents of Discipline to Universities(No.B16017).

语种：英文

中文关键词：single-atom site catalysts(SACs);alkenes;alkynes

摘要：The addition and substitution reactions across a variety of alkenes and alkynes have been playing an important role in organic synthesis.In particular,catalyses enabled by homogeneous complexes as well as heterogenous nanomaterials have been much received attentions over decades.Along with these blooming progresses in these fields,single-atom site catalysts(SACs)exhibit outstanding performances in terms of reactivity and selectivity,thus providing a new powerful strategy to upgrade these bulk chemicals.Herein,we summarize the reactions of alkenes and alkynes enabled by SACs,in which catalytic hydrogenation,hydrosilylation,hydroboration,hydroformylation,and cross coupling have been included.Moreover,preparations and fine structures of the corresponding SACs have been described,therefore providing a better understanding and overview to address the origin of catalytic activity in the reported examples.