文献类型：期刊文献

中文题名：The Preparation and Application of two New Types of Oxazaborolidines

英文题名：The preparation and application of two new types of oxazaborolidines

作者：Rong, GB; Li, XM; Zhang, Y

机构：[1]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China

年份：2000

卷号：0

期号：5

起止页码：381

中文期刊名：中国化学快报：英文版

外文期刊名：CHINESE CHEMICAL LETTERS

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000087193800002)】；CSCD:【CSCD2011_2012】；

基金：This work was supported by, the NNSFC.!(29972012)

语种：英文

中文关键词：Oxazborolidine;asymmetric;catalytic;reduction;prochiral;ketone.

外文关键词：oxazaborolidine; asymmetric catalytic reduction; prochiral ketone

摘要：Two new type of 1,3,2-oxazaborolidines were prepared from (Is,2s)-2-amino-1-(4-nitrophenyl)-propane-1-3-diol and were used as catalyst in the asymmetric reduction of acetophenone. The influence of the reaction temperature as well as the effect of the structure of catalyst on the enantioselectivity was investigated. The origin of the products' configuration was discussed.