文献类型：期刊文献

英文题名：Synthesis and capacitive performance of two-dimensional sandwich-like graphene/nitrogen-doped carbon nanoparticle composites with tunable textural parameters and nitrogen content

作者：Zhou, Min[1];Pu, Fan[1];Chen, Hao[1];Wang, Zhao[1];Zhang, Haiyong[1];Guan, Shiyou[1]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China

年份：2013

卷号：37

期号：12

起止页码：4148

外文期刊名：NEW JOURNAL OF CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000326984000047)】；

基金：The authors are grateful for the financial support from the National Natural Science Foundation of China (No. 21274043).

语种：英文

摘要：Two-dimensional sandwich-like graphene/nitrogen-doped carbon nanoparticle (G/N-doped C) composites with tunable textural parameters such as the specific surface area and the specific pore volume, and nitrogen content have been successfully prepared using graphene/porous SiO2 composites as a template, and ethylenediamine (EDA) and carbon tetrachloride (CTC) with different weight ratios as nitrogen-containing carbon precursors using a simple nanocasting technology. The capacitive performance of the obtained materials has been tested in 1 M H2SO4 aqueous electrolyte. The optimum EDA to CTC weight ratio required for excellent capacitive performance is around 0.4. The G/N-doped C composites prepared with the EDA to CTC weight ratio of 0.4 exhibit a high capacitance of up to 189 F g(-1) at a current density of 0.1 A g(-1), attributed to the co-contribution of double layer capacitance and pseudocapacitance. They also show excellent rate capability (104 F g(-1) remained at 15 A g(-1)) and cycle durability (nearly no capacity decay over 5000 cycles), making them promising electrode materials for supercapacitors.