文献类型：期刊文献

英文题名：Palladium-Catalyzed Direct Regioselective ortho-Phosphonation of Aromatic Azo Compounds with Dialkyl Phosphites

作者：Hong, Gang;Mao, Dan;Wu, Shengying;Wang, Limin[1]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2014

卷号：79

期号：21

起止页码：10629

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20144700215529);WOS:【SCI-EXPANDED(收录号:WOS:000344638200067)，CCR-EXPANDED(收录号:WOS:000344638200067)】；

基金：This research was financially supported by the National Nature Science Foundation of China (21272069, 20672035) and the Fundamental Research Funds for the Central Universities and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：Regioselectivity - Palladium

摘要：An efficient palladium-catalyzed regioselective CP bond formation of azo compounds through CH bond functionalization using dialkyl phosphites as phosphorus source under mild conditions was developed. A series of both symmetrical and unsymmetrical azoarenes were successfully phosphonylated through this procedure with tolerance of a broad range of functional groups.