文献类型：期刊文献

中文题名：碳酸乙烯酯合成3-氨基-2-噁唑烷酮的热力学分析

英文题名：THERMODYNAMIC ANALYSIS OF 3-AMINO-2-OXAZOLIDINONE SYNTHESIS FROM ETHYLENE CARBONATE AND HYDRAZINE

作者：曹宗彬[1];丁同梅[1];黄婕[1];田恒水[1]

机构：[1]华东理工大学化工学院,上海200237

年份：2017

卷号：34

期号：6

起止页码：12

中文期刊名：精细石油化工

外文期刊名：Speciality Petrochemicals

收录：北大核心:【北大核心2014】；CSCD:【CSCD2017_2018】；

语种：中文

中文关键词：碳酸乙烯酯;水合肼;3-氨基-2-噁唑烷酮;合成;热力学

外文关键词：3-amino-2-oxazolidinone; ethylene carbonatel hydrazine; synthesis; thermodynamic

摘要：采用碳酸乙烯酯与水合肼为原料合成了3-氨基-2-噁唑烷酮,采用Benson基团贡献法和Joback法对反应的热力学进行分析,计算了反应焓变、吉布斯自由能和反应平衡常数。
3-Amino-2-oxazolidinone is an important raw material for the synthesis of furazolidone.This article put forward a new synthesis process of using ethylene carbonate and hydrazine as raw materials.The reaction thermodynmic was analyzed by Benson Group Contribution method and Joback method.The reaction heat,Gibbs free energy and equilibrium constants of the reaction calculated by the group contribution method and the obtained results can supply guidance for the experimental research and the process scale-up.